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Ligand effects in enantioface differentiating 1,4 addition to 1,3 diphenyl-2 propen-1 one

✍ Scribed by François Leyendecker; Francis Jesser; Dominique Laucher


Book ID
104219997
Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
187 KB
Volume
24
Category
Article
ISSN
0040-4039

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✦ Synopsis


The extent of enantiomeric excess in the 8-methylation of chalcone ~___~ by ckira7, cuppates is shown to depend strongly on small structural modifications of the ligands, all of which are derived from the basic carbon framework of L-prolinol. Enantiomepic excesses up to 88% have been realised.


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## Abstract Synthesis and free radical polymerization of 1‐(4‐methacryloylaminophenyl)‐3‐phenyl‐2‐propen‐1‐one (2), 1‐[4‐(6‐methacryloylaminohexanoylamino)phenyl]‐3‐phenyl‐2‐propen‐1‐one (7) and 1‐[4‐(11‐methacryloylaminoundecanoylamino)phenyl]‐2‐propen‐1‐one (8) are described. The monomers and a m