Ligand effects in enantioface differentiating 1,4 addition to 1,3 diphenyl-2 propen-1 one
✍ Scribed by François Leyendecker; Francis Jesser; Dominique Laucher
- Book ID
- 104219997
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- French
- Weight
- 187 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
The extent of enantiomeric excess in the 8-methylation of chalcone ~___~ by ckira7, cuppates is shown to depend strongly on small structural modifications of the ligands, all of which are derived from the basic carbon framework of L-prolinol. Enantiomepic excesses up to 88% have been realised.
📜 SIMILAR VOLUMES
## Abstract Synthesis and free radical polymerization of 1‐(4‐methacryloylaminophenyl)‐3‐phenyl‐2‐propen‐1‐one (2), 1‐[4‐(6‐methacryloylaminohexanoylamino)phenyl]‐3‐phenyl‐2‐propen‐1‐one (7) and 1‐[4‐(11‐methacryloylaminoundecanoylamino)phenyl]‐2‐propen‐1‐one (8) are described. The monomers and a m