Ligand dissociation from mono-substituted derivatives of hexacarbonylchromium (Cr(CO)5L, L P(C6H5)3, P(C4H9)3, P(OCH3)3, P(OC6H5)3, and As(C6H5)3)
✍ Scribed by Michael J. Wovkulich; Jim D. Atwood
- Book ID
- 108354437
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 946 KB
- Volume
- 184
- Category
- Article
- ISSN
- 0022-328X
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Ubergangsmetallcluster-Komplexe mit schweren Chalkogenen als Liganden konnten als Ausgangsverbindungen fur neue Materialien dienen, insbesondere fur Verbindungen niedriger Dimensionalitat und guter Leitungseigenschaften"'. Einige losliche binare Selenidometallate wie [Fe2Se121ze121, [W2Se9]2e['1, [W
Siemens AED diffractometer (MoKn): 2 (diethyl ether solvate): monoclinic, P2,/n, a = 12.250(1), h=42.913(3), c = 14.665(1)A, p=91.34(1)", V=7707(l)A3, puled= 1.450 g ~m -~, p=3.59 cm-', 2 = 4 ; 3 5 2 8 5 4 2 " , total number of reflections 8847, 4967 observed with I 2 3a(l), R =0.068, R,, =0.070. 4