𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Lifetimes and collisional self-quenching rates for C2H2Ã 1Au (v′3 = 0 to 4)

✍ Scribed by D. Wolff; H. Zacharias


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
384 KB
Volume
174
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis


Time-resolved laser-induced fluorescence is used to monitor the population in excited rovibronic levels of the A 'A, state of CzH2 in u; ~0 to 4. Double-exponential fluorescence decays are observed in all excitation lines. From the pressure-dependent decay rates, zero-pressure lifetimes and selfquenching rates are derived.


📜 SIMILAR VOLUMES


Radiative lifetime, electronic quenching
✍ Glenn Lo; R. Beaman; D.W. Setser 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 708 KB

A microwave discharge in a SOCl,/Ar mixture has been developed as a source for kinetic studies of the SO(A 3110,,,z) states in a flow reactor using the laser-induced fluorescence method. The radiative lifetime of SO(A 'r&, v' =O) for a 300 K Boltzmann distribution of rotational and spin-orbit states

Synthesis and Structure of [Sn4Se11]6–,
✍ Anja Loose; William S. Sheldrick 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 205 KB 👁 2 views

Reaction of A 2 CO 3 (A = K, Rb) with Sn and Se in an H 2 O/CH 3 OH mixture at 115±130 °C affords the isotypic selenidostannates(IV) A 6 Sn 4 Se 11 ´x H 2 O (A = K, x = 8) 1 and 2 whose discrete [Sn 4 Se 11 ] 6± anions each contain two corner-bridged ditetrahedral [Sn 2 Se 6 ] 4± species. Similar re

Theoretical study of self-exchange elect
✍ Dongju Zhang; Bingyou Zhuang; Dacheng Feng; Chengbu Liu 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 400 KB 👁 2 views

Based on an activation model, a available scheme to calculate the rate of the electron-transfer reaction between transition-metal complexes in aqueous solution is presented. Ab initio technique is used to determine the electron-transfer reactivity of the type M(H 2 O) 2+/3+ 6 of transition-metal com