Librational spectra of water molecules in Ni, Co and Fe dichloride hydrates
โ Scribed by P. Diatto; M. Martini; G. Spinolo
- Book ID
- 107814709
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 436 KB
- Volume
- 49
- Category
- Article
- ISSN
- 0022-3697
No coin nor oath required. For personal study only.
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In the isomorphous hydrates MS0 4 -Hz0 (M = Mn, Co. Ni, 251). where M-0~ distance is the only variable, the frequencies of the wagging, rocking and bending modes of water and of metal-oxygen stretching have been shown to correlate smoothly with the distance r(M-O\V). Quantitative relations have been
Force constants of the water molecules in the crystal hydrates (M = Cu, Fe, Mn, Ba, Co) were MCl 2 AE 2H 2 O analyzed using IR and Raman spectral data. The water intermolecular force constants and wavenumbers for the rock and translation vibrations were calculated using the relationship between chan