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Lewis-Säure-vermittelte Bildung von (±)-(cis)-2,6-Dimethyl-4,4-diphenyl-1,3-dioxan aus (±)-1,1-Diphenylbutan-1,3-diol

✍ Scribed by Prof. Dr. Franz Bracher; Thomas Litz


Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
172 KB
Volume
337
Category
Article
ISSN
1615-4150

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Bildung von 5,6-Dihydro-1,3(4H)-thiazin-
✍ Christjohannes Jenny; Heinz Heimgartner 📂 Article 📅 1989 🏛 John Wiley and Sons 🌐 German ⚖ 538 KB

## Formation of Methyl 5,6-Dihydro-1,3(4H)-thiazine-4-carboxylates from 4-Allyl-1,3-thiazol-5(4H)-ones The reaction of N -[ 1 -(N+V-dimethylthiocarbamoyI)-l -methyl-3-butenyl]benzamid (1) with HC1 or TsOH in MeCN or toluene yields a mixture of 4-allyl-4-methyl-2-phenyl-1,3-thiazol-5(4H)-one (5a) a