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Lewis Base-Catalyzed Cyanomethylation of Carbonyl Compounds with (Trimethylsilyl)acetonitrile.

✍ Scribed by Yoshikazu Kawano; Nobuya Kaneko; Teruaki Mukaiyama

Publisher: John Wiley and Sons
Year: 2006
Weight: 20 KB
Volume: 37
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200616039

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✦ Synopsis

Abstract

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## Abstract A new __Lewis__ base catalyzed aldol reaction of trimethylsilyl enolates with aldehydes is established in DMF or pyridine solvent by using a __Lewis__ base such as lithium diphenylamide (__Tables 4__ and __5__) or lithium 2‐pyrrolidone (__Tables 6__–__8__). The effect of solvent suggest