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Lewis Acid Properties of Tris(pentafluorophenyl)borane. Structure and Bonding in L−B(C6F5)3 Complexes⊥

✍ Scribed by Jacobsen, Heiko; Berke, Heinz; Döring, Steve; Kehr, Gerald; Erker, Gerhard; Fröhlich, Roland; Meyer, Oliver

Book ID
111937164
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
258 KB
Volume
18
Category
Article
ISSN
0276-7333

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## Abstract The scope of the B(C~6~F~5~)~3~‐catalyzed hydrosilylation of (X)Ph–CH=O and (X)Ph–C(R)=O was expanded to include a large set of substitutents (X = H, __p__‐Me, __o__‐Me, __p__‐F, __o__‐F, __p__‐Cl, __p__‐Br, __p__‐NO~2~, __m__‐NO~2~, __p__‐Et; R = Me or CF~3~). Reactions proceed at room