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Lewis acid-induced nucleophilic substitution reactions of aliphatic nitro compounds with carbon nucleophiles

โœ Scribed by Ono, Noboru; Yanai, Tetsuya; Kamimura, Akio; Kaji, Aritsune


Book ID
121876997
Publisher
The Royal Society of Chemistry
Year
1986
Tongue
English
Weight
181 KB
Volume
16
Category
Article
ISSN
0022-4936

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Lewis acid catalyzed substitution of all
โœ Hideyoshi Miyake; Kimiaki Yamamura ๐Ÿ“‚ Article ๐Ÿ“… 1986 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 225 KB

The nitro group in allylic nitro compounds is replaced by cyano group on treatment with cyanotrimethylsilane in the presence of Lewis acid. Allylic nitro compounds are easily prepared by well established procedures with carbon-carbon bond forming reaction under mild conditions 1,2) and the nitro gr