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Lewis Acid-Catalyzed Regio- and Stereoselective Hydrosilylation of Alkenes with Trialkylsilanes

✍ Scribed by Song, Young-Sang; Yoo, Bok Ryul; Lee, Gyu-Hwan; Jung, Il Nam

Book ID: 120553632
Publisher: American Chemical Society
Year: 1999
Tongue: English
Weight: 132 KB
Volume: 18
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om990220p

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## Abstract Transition‐metal‐catalyzed coupling of two different CC π components through a metallacycle intermediate is a highly atom economical method to construct CC bonds in organic synthesis. The metal‐catalyzed coupling of an alkene and alkyne generally gives an Alder‐ene or reductive coupli