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Palladium-Catalyzed Regio- and Stereoselective Hydrosilylation of Electron-Deficient Alkynes

โœ Scribed by Sumida, Yuto; Kato, Tomoe; Yoshida, Suguru; Hosoya, Takamitsu


Book ID
126219862
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
498 KB
Volume
14
Category
Article
ISSN
1523-7060

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Regio- and stereoselective hydrosilylati
โœ Palle J. Pedersen; Jonas Henriksen; Charlotte H. Gotfredsen; Mads H. Clausen ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 277 KB

Regio-and stereoselective hydrosilylation of terminal alkynes on solid support using diisopropyl hydrosilanes yielding b-(E)-vinyl silanes with excellent selectivity is reported. The hydrosilylation is catalyzed by Pt(DVDS)/P( i BuNCH 2 CH 2 ) 3 N (DVDS = 1,3-divinyl-1,1,3,3-tetramethyl-disiloxane),