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Lewis acid-catalysed conversion of homoadamantene into 2-methyladamantane

โœ Scribed by Majerski, Zdenko; Mlinari?, Katica

Book ID
121237479
Publisher
The Royal Society of Chemistry
Year
1972
Tongue
English
Weight
141 KB
Volume
18
Category
Article
ISSN
0022-4936

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Lewis acid catalysed [2+2] cycloreversio
Lewis acid catalysed [2+2] cycloreversion of cookson's cage ketones under ambient conditions: model system for light energy conversion
โœ Goverdhan Mehta; D. Sivakumar Reddy; A. Veera Reddy ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 200 KB

Design of 'push-pull' Cookson's cage ketones and their quantitative [2+2] cycloreversion to cis, SJJ, cis-triquinanes at room temp, under Lewis acid catalysis, is reported. This observation has promising ramifications on the utility of 1 z 2 system for reversible storage of solar energy.