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Lewis acid catalysed [2+2] cycloreversion of cookson's cage ketones under ambient conditions: model system for light energy conversion

✍ Scribed by Goverdhan Mehta; D. Sivakumar Reddy; A. Veera Reddy


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
200 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis


Design of 'push-pull' Cookson's cage ketones and their quantitative

[2+2] cycloreversion to cis, SJJ, cis-triquinanes at room temp, under Lewis acid catalysis, is reported. This observation has promising ramifications on the utility of 1 z 2 system for reversible storage of solar energy.