Pb 4 BiO 4 PO 4 was prepared by heating a stoichiometric mixture of (NH 4 ) 2 HPO 4 , PbO, and Bi 2 O 3 at 700°C for 4 days with intermediate grinding. The material melts congruently at 805°C; single crystals were obtained by slow cooling of a melt. The compound is triclinic, P1 , a ؍ 6.215(1) A s
✦ LIBER ✦
Lead alkali apatites without hexad anion: The crystal structure of Pb8K2(PO4)6
✍ Scribed by M. Mathew; W.E. Brown; M. Austin; T. Negas
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 588 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0022-4596
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compound (III) crystallizes in the monoclinic space group P2 1 /c with Z = 2 (single crystal XRD). The structure contains oligomeric tetrahedral anions based on six-membered rings of four BO 4 and two PO 4 tetrahedra with additional branchings by hydrogenphosphate groups (two cyclic, four open branc