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Late-Transition-Metal Complexes of BINOL-Derived Salens: Synthesis, Structure, and Reactivity

✍ Scribed by DiMauro, Erin F.; Kozlowski, Marisa C.

Book ID
111686837
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
135 KB
Volume
21
Category
Article
ISSN
0276-7333

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## Abstract Modification of the multistep synthesis of the previously described bis[5‐(diphenylphosphanyl)pyrazol‐1‐yl)]methane (bppzm, 1) produces the novel diphosphane (diphenylphosphanyl)‐[5‐(diphenylphosphanyl)pyrazol‐1‐yl](pyrazol‐1‐yl)methane (p4m, 2). Treatment of this ligand with [MCl~2~(Ph