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Catalysis of the Michael Addition Reaction by Late Transition Metal Complexes of BINOL-Derived Salens

✍ Scribed by Annamalai, Venkatachalam; DiMauro, Erin F.; Carroll, Patrick J.; Kozlowski, Marisa C.

Book ID
121277728
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
317 KB
Volume
68
Category
Article
ISSN
0022-3263

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2,4-Pentanedionato)copper(I) and bis(2,4\_pentanedionato)copper(II) together with boron trifluoride etherate catalyze Michael addition of B-dicarbonyls to cyclohexenone, cyclopentenone, Z-methylcyclopentenone, and 3-thienylidenemalonaldehyde. Carbon-carbon bond formation is of prime importance in s