Laser photolysis of ICl. A time-resolved LMR measurement of Cl(2P12) relative yield
โ Scribed by T.S. Mashnin; A.V. Chernyshev; L.N. Krasnoperov
- Book ID
- 103036470
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 451 KB
- Volume
- 207
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
Laser photolysis of chlorine-containing molecules at 1= 248 and 3 5 I nm has been performed using time-resolved laser magnetic resonance to detect Cl(2P,,2) and Cl(2P312) chlorine atoms. Relative yields of spin-orbit excited chlorine atoms, /J'= ~~~~z~,,,~l/~I~~~2~,,,~l+~~~~z~,,~~lJ, h ave been meas
Time-resolved LMR combined with fast magnetic field jump has been employed to study collisional quenching of the upper state of a chlorine atom fine structure (C1(32P,,2)). The following quenching rate constants have been obtained: (1.8 \*0.4)x lo-", (1.7\*0.4)~10-'~, (7.4+2.6)x10-'3 and ~1O-l~ cm3/