✦ LIBER ✦
Measurement of Cl (2P12) quantum yield for the photodissociation of NOCl, ICl, PCl3, Cl2O and COCl2
✍ Scribed by A.I. Chichinin
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 399 KB
- Volume
- 209
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Laser photolysis of chlorine-containing molecules at 1= 248 and 3 5 I nm has been performed using time-resolved laser magnetic resonance to detect Cl(2P,,2) and Cl(2P312) chlorine atoms. Relative yields of spin-orbit excited chlorine atoms, /J'= ~~~~z~,,,~l/~I~~~2~,,,~l+~~~~z~,,~~lJ, h ave been measured for the photodissoclation of NOCl (A=351 nm), NOCI (248 nm), ICI (248 nm), PCll (248 nm), Cl,0 (248 nm), COCll(248 nm) yielding the following values respectively: 9Oi IO, 88k 12, 67&5,44&3, 18k3, <Y/o.