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Laser photolysis of C2H2 and CF3C2H at 193 nm: Production of C2(d3Πg and CH(A2Δ) and their quenching by Xe

✍ Scribed by Hideo Okabe; R.J. Cody; J.E. Allen Jr.


Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
678 KB
Volume
92
Category
Article
ISSN
0301-0104

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Kinetics of the reactions H + C2H4 → C2H
✍ Alfred Sillesen; Emil Ratajczak; Palle Pagsberg 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 527 KB

Formation of methyl radicals via the consecutive reactions H+C2H,+M+C2H,+M ( I ) and H+CLH,+CH,+CH3 (?a) was initiated by pulse radiolysis of IO-100 mbar Hz in the presence of ethylene. The kinetics of CH, were studied by monitoring the transient infrared absorption at the Q( 3, 3) line of the u,=O+