✦ LIBER ✦

Laser photodissociation of Hg(CH3)2: Infrared emission studies of vibrational and rotational excitation in the CH3 fragments

✍ Scribed by Steven L. Baughcum; Stephen R. Leone

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 507 KB
Volume: 89
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(82)80038-9

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✦ Synopsis

Single-photon dissociation of Hg(CH& at 248 and 193 nm produces CH, radicals with substanual ewxauon in Ihe ~2 out4planc bend and the uj antisymmetric stretch. At 218 nm the antisymmetnc stretch excdation is charackrized by a 1200-1500 K rotational temperature and a nbratiorul dlslrlbuuon sl : ~2 : ~3 of I 0 : 0.ZrO.l : O.OS*O.OS.

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