Laser-Induced Luminescence Studies and Crystal Structure of the Europium(III) Complex of 1,4,7,10-Tetrakis(carbamoylmethyl)-1,4,7,10-tetraazacyclododecane. The Link between Phosphate Diester Binding and Catalysis by Lanthanide(III) Macrocyclic Complexes
✍ Scribed by Amin, Shahid; Voss, David A.; Horrocks, William DeW.; Lake, Charles H.; Churchill, Melvyn Rowen; Morrow, Janet R.
- Book ID
- 121360950
- Publisher
- American Chemical Society
- Year
- 1995
- Tongue
- English
- Weight
- 938 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0020-1669
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## Abstract The lead(II) coordination properties of the tetrapodal ligand DOTAM [1,4,7,10‐tetrakis(carbamoylmethyl)‐1,4,7,10‐tetraaza‐cyclododecane] have been investigated both in the solid state and in solution in order to ascertain the stereoactivity of the lone pair and to rationalize the struct
## Abstract Complexation of the lanthanides Eu^3+^, Gd^3+^, and Tb^3+^ with 1,4,7,10‐tetrakis(carboxymethyl)‐1,4,7,10‐tetraazacyclododecane (dota) has been studied in solution by using potentiometry, luminescence spectrometry, and EXAFS. Three series of successive complexes were characterized by at