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Laser-induced fluorescence measurement of the vibrational distribution of CS formed in the reaction O + CS2 → CS + So

✍ Scribed by P.N. Clough; J. Johnston

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
418 KB
Volume
71
Category
Article
ISSN
0009-2614

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📜 SIMILAR VOLUMES

Measurements of the bimolecular rate con
Measurements of the bimolecular rate constants for S + O2 → SO + O and CS2 + O2 → CS + SO2 at high temperatures
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The bimolecular reactions in the title were measured behind shock waves by monitoring the 0-atom production in COS-02-Ar and CS2-02-Ar mixtures over the temperature range between 1400 and 2200 K. A value of the rate constant for S + O2 -+ SO f 0 was evaluated to be (3.8 2 0.7) x 10" cm3 mol-' s-' be

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✍ G. Hancock; C. Morley; I.W.M. Smith 📂 Article 📅 1971 🏛 Elsevier Science 🌐 English ⚖ 422 KB

The relative raxes at which 0 + CS +CO + S populates individual vibrational levels of CO have been determined (a) from infrared chemiluminescence esperiments, and (b) by using a cw CO laser to measure CO vibrational distibutions produced when mixtures of CS2 + O2 are flash photolysed.