It is found that the triplet-triplet energy transfer (ET) reaction between triplet benzophenone ('BP\*) and l-naphthol (ROH) is competitive with the hydrogen atom abstraction (HA) reaction. The rate constant of ET is enhanced with an increase of solvent polarity while that of HA is reduced. A possib
Laser flash photolysis study of the hydrogen atom transfer reaction from triplet 1-naphthol to ground benzophenone
β Scribed by Shizuka, Haruo; Hagiwara, Hiroyuki; Fukushima, Masaru
- Book ID
- 120634957
- Publisher
- American Chemical Society
- Year
- 1985
- Tongue
- English
- Weight
- 1013 KB
- Volume
- 107
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The rate constants (kHA and klQ) for the hydrogen atom abstraction (HA) and induced-quenching (IQ) processes between triplet benzophenone (3Bp \*) and halogenated toluenes (XTL) were determined by means of nanosecond laser flash photolysis techniques. It was found that the klQ value increased propor
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