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Laser Flash Photolysis Studies of Oxygen and Sulfur Atom Transfer Reactions from Oxiranes and Thiiranes to Singlet Carbenes1

✍ Scribed by Pezacki, John Paul; Wood, Paul D.; Gadosy, Timothy A.; Lusztyk, Janusz; Warkentin, John

Book ID
115476533
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
303 KB
Volume
120
Category
Article
ISSN
0002-7863

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Solvent dependence of triplet energy tra
Solvent dependence of triplet energy transfer reaction competing with hydrogen atom abstraction between triplet benzophenone and 1-naphthol studied by laser flash photolysis
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It is found that the triplet-triplet energy transfer (ET) reaction between triplet benzophenone ('BP\*) and l-naphthol (ROH) is competitive with the hydrogen atom abstraction (HA) reaction. The rate constant of ET is enhanced with an increase of solvent polarity while that of HA is reduced. A possib