Laser Flash Photolysis of Pyridine N-Oxide: Kinetic Studies of Atomic Oxygen [O(3P)] in Solution
β Scribed by Bucher, Gotz; Scaiano, J. C.
- Book ID
- 121379317
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 337 KB
- Volume
- 98
- Category
- Article
- ISSN
- 0022-3654
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π SIMILAR VOLUMES
A laser photolysis-long path laser absorption (LP-LPLA) experiment has been used to determine the rate constants for H-atom abstraction reactions of the dichloride radical anion (Cl 2 Οͺ ) in aqueous solution. From direct measurements of the decay of Cl 2 Οͺ in the presence of different reactants at p
Rate constants for the gas phase reactions of O(3P) atoms with a series of symmetric aliphatic ethers have been determined using the flash photolysis resonance fluorescence technique over the temperature range 240-400 K. The Arrhenius parameters derived from these data are (in units of cm3 molecule-