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Laser flash photolysis of iodine-iodide mixture in hydroxylic solvent. Evidence for the existence of the radical anion I

โœ Scribed by Philippe Fornier de Violet; Roland Bonneau; Jacques Joussot-Dubien

Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
455 KB
Volume
28
Category
Article
ISSN
0009-2614

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Laser flash photolysis of iodine-iodide
Laser flash photolysis of iodine-iodide mixture in tertiobutanol solution. Evidence for the existence of the radical anion
โœ Philippe Fornier de Violet ๐Ÿ“‚ Article ๐Ÿ“… 1976 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 287 KB

Leer flash &&o&is of a concentrated iodine solution in the presence of I-ions in tertiobutanol gives rise to a transient absorption band with a maximum at 540 m-n. At equilibrium the soIution contains mtiy Iz, 1; and to a Iesser extent I;. The actinic flash at 529 IIIY~ photodissociates the iodine i