Lariat ether alcohols based on dibenzo-16-crown-5
โ Scribed by Richard A. Bartsch; Leah P. Bitalac; Charles L. Cowey; Sadik Elshani; Mi-Ja Goo; Vincent J. Huber; Sheryl N. Ivy; Youngchan Jang; Russell J. Johnson; Jong Seung Kim; Elzbieta Luboch; Joseph A. Mcdonough; Michael J. Pugia; Byungki Son; Qiang Zhao
- Book ID
- 102894010
- Publisher
- Journal of Heterocyclic Chemistry
- Year
- 2000
- Tongue
- English
- Weight
- 787 KB
- Volume
- 37
- Category
- Article
- ISSN
- 0022-152X
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โฆ Synopsis
Abstract
Synthetic routes to fortyโfour dibenzocrown ether alcohols are reported. The new crown ether com pounds are based on a symโdibenzoโ16โcrownโ5 platform. Most have a hydroxy group and an alkyl, aryl, aralkyl, alkenyl, alkynyl, or perfluoroalkyl group on the central carbon of the threeโcarbon bridge. Others have substituted benzene rings and either a hydroxy or โO(CH~2~)~n~OH group attached to the central carbon of the threeโcarbon bridge.
๐ SIMILAR VOLUMES
## Abstract Synthetic routes to fortyโseven dibenzoโ16โcrownโ5 compounds with pendant carboxylic acid groups are reported. When taken together with previously described lariat ether carboxylic acids, these new compounds provide several series with systematic structural variations including changes
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a โFull Textโ option. The original article is trackable v
## Abstract Structurally related dibenzoโ16โcrownโ5 lariat ethers with pendant ester and ether groups are prepared. Structural variations within the series of alkyl lariat ether esters include changes in the Oโalkyl group, attachment site and nature of the lipophilic group, and length of the spacer