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Synthesis of lariat ether carboxylic acids based on dibenzo-16-crown-5

✍ Scribed by Richard A. Bartsch; Charles L. Cowey; Sadik Elshani; Mi-Ja Goo; Vincent J. Huber; Sheryl N. Ivy; Russell J. Johnson; Jong Seung Kim; Elzbieta Luboch; Joseph A. Mcdonough; Michael J. Pugia; Byungki Son; Qiang Zhao

Publisher
Journal of Heterocyclic Chemistry
Year
2001
Tongue
English
Weight
192 KB
Volume
38
Category
Article
ISSN
0022-152X

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✦ Synopsis

Abstract

Synthetic routes to forty‐seven dibenzo‐16‐crown‐5 compounds with pendant carboxylic acid groups are reported. When taken together with previously described lariat ether carboxylic acids, these new compounds provide several series with systematic structural variations including changes in the identity and attachment site(s) of one or more lipophilic groups and the length of the spacer that connects the carboxylic acid group to the polyether framework.

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