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Lanthanum metal-assisted deoxygenative coupling of alcohols

✍ Scribed by Toshiki Nishino; Yutaka Nishiyama; Noboru Sonoda

Publisher
Elsevier Science
Year
2002
Tongue
French
Weight
61 KB
Volume
43
Category
Article
ISSN
0040-4039

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✦ Synopsis

It was found that the deoxygenative coupling of alcohols efficiently proceeded by treatment with lanthanum metal and chlorotrimethylsilane in the presence of a catalytic amount of iodine. This coupling reaction was accelerated by the addition of a catalytic amount of copper(I) iodide.

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