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Lanthanides benzimidinates: initiators or real catalysts for the ε-caprolactone polymerization

✍ Scribed by Denise Barbier-Baudry; Aicha Bouazza; Claire Hélène Brachais; Alain Dormond; Marc Visseaux

Book ID
101305661
Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
57 KB
Volume
21
Category
Article
ISSN
1022-1336

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Lanthanide Thiolate Complexes: Novel Ini
Lanthanide Thiolate Complexes: Novel Initiators for Ring-opening Polymerization of ε-Caprolactone
✍ Hong-Mei Sun; Huan-Rong Li; Chang-Sheng Yao; Ying-Ming Yao; Hong-Ting Sheng; Qi 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 114 KB

## Abstract The ring‐opening polymerization (ROP) of __ε__‐caprolactone (__ε__‐CL) using lanthanide thiolate complexes [(CH~3~C~5~H~4~)~2~Sm(μ‐SPh)(THF)] ~2~ (1) and Sm(SPh)~3~(HMPA)~3~ (2) as initiators has been investigated for the first time. Both of 1 and 2 were found to be highly efficient ini