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A Recoverable, Metal-Free Catalyst for the Green Polymerization of ε-Caprolactone

✍ Scribed by Wilson, Benn C.; Jones, Christopher W.


Book ID
120793093
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
114 KB
Volume
37
Category
Article
ISSN
0024-9297

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A germyl-bridged lanthanocene chloride, Me 2 Ge( t Bu-C 5 H 3 ) 2 LnCl (Ln ¼ Nd; (Cat-Nd), was prepared and successfully used as single catalyst to initiate the ringopening polymerization of e-caprolactone (e-CL) for the first time. Under mild conditions (60 C,[e-CL]/[Ln] ¼ 200, 4 h), Cat-Nd efficie