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Lanthanide-induced shifts in the structural elucidation of β-hydroxydecalones

✍ Scribed by Rossana A. Schenato; Éverton M. dos Santos; Paulo F. B. Gonçalves; Beatriz S. M. Tenius; Eduardo R. de Oliveira; Ignez Caracelli; Julio Zukerman-Schpector

Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
173 KB
Volume
41
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The use of Eu(fod)~3~ in the analysis of the ^1^H and ^13^C NMR spectra of cis and trans‐fused β‐hydroxydecalones is described. The relative configuration of the substituents is discussed using the PMLIS algorithm to determine the lanthanide (Eu) ion position in the complex in an effective axially symmetric model. The conformations of two cis‐decalones are also discussed. Copyright © 2002 John Wiley & Sons, Ltd.

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