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Lamellar Copper(I) Thiocyanate-Based Coordination Polymers containing the Alkali Cation ligating Thiacrown Ether 1,10-Dithia-18-crown-6

✍ Scribed by T. Röttgers; W. S. Sheldrick

Book ID: 101364632
Publisher: John Wiley and Sons
Year: 2001
Tongue: German
Weight: 298 KB
Volume: 627
Category: Article
ISSN: 0372-7874
DOI: 10.1002/1521-3749(200108)627:8<1976::aid-zaac1976>3.0.co;2-x

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The lamellar coordination polymer 2 R [CuI(1,10DT18C6)] (1) (1,10DT18C6 ‫؍‬ 1,10-dithia-18-crown-6) may be prepared by reaction of CuI with the thiacrown ether in acetonitrile. 1 crystallizes in the monoclinic space group P2 1 /n with a ‫؍‬ 10.764(2), b ‫؍‬ 14.317(3), and c ‫؍‬ 12.335(3) A > , ‫؍‬ 9

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