L'action de L'ammoniaque et D'amines sur la 3. 4. Dinitrodiméthylaniline et la 3. 4. Dinitrodiéthylaniline
✍ Scribed by P. van Romburgh
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 212 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0165-0513
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📜 SIMILAR VOLUMES
Coinmz nous l'avox dCjB dCcrit [2], la rhction entre dichlorophCnylp~iospliine (P trivalent) et alcool a-acCtylCnique conduit B un ester allknyl-phknyl-pliosphinique qui, p3r hydrolys-acide, fournit l'acide phosphinique correspondant : Centre de spcctroscopie dc masse tlc 1'UnivcrsitC dc Genhvc. 2
The thermal decomposition of phenyl carbazate results in formation of 4-amino urazole. The same compound is formed in reactions which according to other authors yield p-urazine. This six-membered cyclic isomer could not be prepared. The structure of 4-amino urazole is confirmed by study of infrared
The reaction of phenylphosphonic oxide with amines and amino‐alcools is described. Under appropriate conditions this reaction yields respectively the corresponding phosphonic mono‐amides and mono‐esters.
Reaction of 2-methyl-2-benzyl-l,2,3,4-tetrahydroisoquinolinium iodide with sodium amide in liquid ammonia yields 76% l-orthotolyl-2-methy1-1,2,3,4-tetrahydroisoquinoline resulting from a Sommelet-Hauser rearrangement. In the same conditions, 2,2-dimethyl-1,2,3,4-tetrahydroisoquinolinium iodide yield