Laboratory measurements of the association rate coefficients of NO+, O+2, N+, and N+2 ions with N2 and CO2 at temperatures between 100 k and 400 k
β Scribed by Seksan Dheandhanoo; Rainer Johnsen
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 454 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0032-0633
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The rdt, cocii~c~cnts and product eon dlsrrlbutlons for rhc reactions ot OH\* and tlzO+ u ith N2\_ 02 h'0 X20 Xc, CO, CO? H2S Jnd 112 hd\c been dctermlned it 194 + 2 K usmg a selcctcd ton ilo\. rubc (SIFT) dppclrnrus These reactIons urre generally found to proLccd b\~ athcr proton or charge trsnsfcr
The kinetics of the reaction of 0 atoms with NO2 was investigated in the temperature range 199-357 K. The value of the rate constant can be expressed by k, = (5.21 kO.50) x lo-'\* exp [(202\*27)lT] cm3 s-' (3~ error). At temperatures below 230 K, the formation of equilibrium concentrations of N204 a