## Abstract The reaction mechanism of the halogen (Cl and Br)‐atom initiated oxidation of C~2~H~4~ was studied using the long path FTIR spectroscopic method in 700 torr of air at 296 ± 2 K. Among the major halogen‐containing products were XCH~2~CHO, XCH~2~CH~2~OH, and XCH~2~CH~2~OOH (X = Cl or B
Laboratory and Theoretical Study of the Oxy Radicals in the OH- and Cl-Initiated Oxidation of Ethene
✍ Scribed by Orlando, John J.; Tyndall, Geoffrey S.; Bilde, Merete; Ferronato, Corinne; Wallington, Timothy J.; Vereecken, Luc; Peeters, Jozef
- Book ID
- 126154372
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 127 KB
- Volume
- 102
- Category
- Article
- ISSN
- 1089-5639
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Using a relative kinetic technique, rate coefficients have been measured, at 296 Ϯ 2 K and 740 Torr total pressure of synthetic air, for the gas-phase reaction of OH radicals with the dibasic esters dimethyl succinate The rate coefficients obtained were (in units of cm 3 molecule Ϫ1 s Ϫ1 ): dimethy
## Abstract A dual‐level direct dynamic method is employed to study the reaction mechanisms of CF~3~CH~2~OCHF~2~ (HFE‐245fa2; HFE‐245mf) with the OH radicals and Cl atoms. Two hydrogen abstraction channels and two displacement processes are found for each reaction. For further study, the reaction m