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Labilization of the 3-carbon hydrogens in chelated (2S)-aspartic acid and erythro- and threo-(2S)-3-methylaspartic acid

✍ Scribed by McClarin, Judith A.; Dressel, Larry A.; Legg, J. Ivan


Book ID
126042253
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
602 KB
Volume
98
Category
Article
ISSN
0002-7863

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The tide compounds were prepared from key intermediates readily obtained by the stereoselective Diels-Alder reaction of (Z)-2-pbenyl-4-[(S)-2,2-dimethyl-l,3dioxolan-4-ylmethylene]-5(4H)-oxazolone, a chiral az-lactone derived from (R)glyceraldehyde and cyclopentadiene.