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Labelling studies of the ring opening of 1-bromo-2-chloro-3,3-dimethylcyclopropene

✍ Scribed by Mark S. Baird

Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
210 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis

upon Tyne , Newcastle upon Vne , NE1 7RU. 1-Bromo-2-chloro-3,3-dimethylcyclopropene reacts with methyl lithium in the presence of 2,3_dimethylbut-2-ene at above -7OOC to give (4); 12 C labelling shows that C-2 of the cyclopropane becomes the centre carbon of the allene.

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