## Abstract An efficient approach to the enantioselective synthesis of a series of amino acids from either bromoacetyl bromide or glycine is described using a [2,3]βsigmatropic rearrangement to establish the stereogenic centre at Cβ2 under mild conditions. Protected allylglycine **5** is a valuable
Labeling of Proteins by Isotopic Amino Acid Derivatives
β Scribed by Christine Zioudrou, Setsuro Fujii and Joseph S. Fruton
- Book ID
- 123670971
- Publisher
- National Academy of Sciences
- Year
- 1958
- Tongue
- English
- Weight
- 366 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0027-8424
- DOI
- 10.2307/89576
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This is the first of five books in the *Amino Acids, Peptides and Proteins in Organic Synthesis* series. Closing a gap in the literature, this is the only series to cover this important topic in organic and biochemistry. Drawing upon the combined expertise of the international "who's who" in amino
Over 10 g of individual ZH,'5N-labeled amino acids was resolved and recovered on a laboratory-scale ion-exchange system from a crude bacterial protein hydrolyzate derived from 20 g of lyophilized cells. The 17 amino acids (cystine was not isolated) were recovered containing less than 1.0% of other c