Komplexone XXXIII. Reaktionsenthalpie und -entropie bei der Bildung der Metallkomplexe von Äthylendiamin- und Diaminocyclohexan-tetraessigsäure
✍ Scribed by G. Anderegg
- Publisher
- John Wiley and Sons
- Year
- 1963
- Tongue
- German
- Weight
- 587 KB
- Volume
- 46
- Category
- Article
- ISSN
- 0018-019X
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✦ Synopsis
Abstract
The enthalphy changes involved in teh formation of teh proton and the metal complexes of enthylenediamine ‐N,N,N^′^,N^′^ tetraacetate ion and trans‐1,2‐diaminocyclohexane‐N,N,N^′^,N^′^‐ tetraacetate ion have been determined using a direct calorimetric method.
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## Abstract The enthalpy changes involved in the formation of the proton and the metal complexes of 1,10‐phenanthroline (phen) and α,α′‐bipyridyl (dip) have been determined, using a direct calorimetric method.
## Abstract The stability constants of the 1 :1 complexes of trimethylenediamine‐N, N, N′ N′ tetraacetate ‘TMTA’ with rare earth trivalent cations have been checked. The heats involved in complex formation have been determined. The thermodynamic data show a similar trend as for those of the EDTA c