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Kleine Ringe, 85. Versuche zur Darstellung von Alkyltri-tert-butyltetrahedranen auf dem Cyclopentadienon-Weg; Synthese der Cyclopentadienone

✍ Scribed by Maier, Günther ;Franz, Lothar Hermann

Publisher: John Wiley and Sons
Year: 1995
Tongue: English
Weight: 820 KB
Volume: 1995
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.199519950119

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✦ Synopsis

Small Rings, 85. — Attempts to Synthesize Alkyltri‐tert‐butyltetrahedranes by the Cyclopentadienone Route; Synthesis of the Cyclopentadienones

Starting from 2‐bromotri‐tert‐butylcyclopentadienone (1) a series of highly substituted cyclopentadienones has been prepared, hoping that they might be suitable candidates for the synthesis of a variety of tetrahedranes with different sterically demanding substituents.

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Kleine Ringe, 86. Versuche zur Darstellung von Alkyltri-tert-butyltetrahedranen auf dem Cyclopentadienon-Weg; photochemisches Verhalten der Cyclopentadienone

✍ Maier, G. ;Franz, L. H. ;Boese, Roland 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 554 KB

Small Rings, 8 6 W -Attempts to Synthesize Alkyltri-tert-butyltetrahedranes by the Cyclopentadienone Route: Photochemical Behavior of the Cyclopentadienones Only the Tetra-tert-butyltetrahedranes 8a-c can be synthesized by photochemical CO extrusion from the corresponding cyclopentadienones 6a-c. Th