Kinetics of(dot NO_2)formation upon the decomposition of nitromethane behind shock waves and the possibility of nitromethane isomerization in the course of the reaction
β Scribed by N. M. Kuznetsov; Yu. P. Petrov; S. V. Turetskii
- Book ID
- 114989551
- Publisher
- Springer
- Year
- 2012
- Tongue
- English
- Weight
- 534 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0023-1584
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Measurements of the NO-catalyzed dissociation of I2 in Ar in incident shock waves were carried out in the temperature range of 700"-1520Β°K and a t total concentrations of 5 X 10-6-6 X mol/cm3, using ultraviolet-visible absorption techniques to monitor the disappearance of 12. It was shown that the m
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Pcroxynitrlc ac~d has been idcntlficd by I~our~cr transform, infrared, long-path spectroscopy as a product of the UVirrndratcd ddutc mi\turcs of llON0, CO, NO, in synthctrc air at 24 L 2Β°C'. The characteristic pcnks of this compound arc idcntrcnl to those obscrvcd by Nikl ct al., in Irr.ulratcd Clz,
The rate of H-atom formation in the thermal decomposition of o-, m-, and p-xylene was studied behind reflected shock waves between 1300 and 1800 K and at pressures of 1.6 to 4 bar by using atomic resonance absorption spectroscopy at 121.6 nm. For the thermal decomposition of p-xylene, m-xylene, and