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ChemInform Abstract: Unprecedented Formation of Isoxazole in the Reaction Between Nitromethane and BF3×Et2O in the Presence of Ethylene.

✍ Scribed by J. A. DAVIES; C. PETERSOHN; V. YU. KUKUSHKIN


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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ChemInform Abstract: The BF3×Et2O-Cataly
✍ S. N. CRANE; D. J. BURNELL 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 42 KB 👁 1 views

The BF 3 •Et 2 O-Catalyzed Reaction of 1,2-Bis[(trimethylsilyl)oxy]cyclobutene and Analogues with Aromatic Ketones. -Aromatic ketones (I) and (V) undergo geminal acylation with cyclobutene (II) and its methylated analogues (VIII). Subsequent rearrangement, especially during aqueous work-up, results