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Kinetics of Triplet-Triplet Annihilation of Mg-Phthalocyanine in Methanol and Deuteromethanol

✍ Scribed by V.V. Sapunov

Book ID
110420156
Publisher
Springer US
Year
2002
Tongue
English
Weight
55 KB
Volume
69
Category
Article
ISSN
0021-9037

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Excimer formation in triplet-triplet ann
Excimer formation in triplet-triplet annihilation reactions of metal (3ππ*) porphyrins and (3ππ*) phthalocyanines
✍ Mark E. Frink; G. Ferraudi πŸ“‚ Article πŸ“… 1986 πŸ› Elsevier Science 🌐 English βš– 269 KB

The triplet-triplet annihilation of the lowest-lying excited states of porphyrins and phthalocyanines has been investigated by laser flash photolysis. Spectroscopic and kinetic evtdence indicates that the lowest-lying triplet dimerizes into excimers at a rate less than diffusion controlled.