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Kinetics of the transformation process of PbSO4 to PbO2 in a lead anodic film

โœ Scribed by Jia-Rong Wang; Guo-Lin Wei


Publisher
Elsevier
Year
1995
Tongue
English
Weight
425 KB
Volume
390
Category
Article
ISSN
1572-6657

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The kinetics of the processes of reducing tetragonal PbO to Pb has been studied by the linear sweep voltammetry (Isv) technique. It was found that the reduction processes of tetragonal PbO are controlled by OH-ion diffusion through the PbSO, membrane besides the limitation of the nucleation and grow

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The crystal structure of tribasic lead sulfate (3PbO โ€ข PbSO 4 โ€ข H 2 O) has been determined by a combination of single crystal X-ray and powder neutron diffraction to R of 0.024. From X-ray data, the space group is P1 , a โ€ซุโ€ฌ 6.378(1), b โ€ซุโ€ฌ 7.454(2), c โ€ซุโ€ฌ 10.308(2) A s , โ€ซุโ€ฌ 75.26(3), โ€ซุโ€ฌ 79.37(3),