𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics of the synthesis of propyl and butyl acrylates in the presence of some heteropolyacids as catalysts

✍ Scribed by Jerzy Skrzypek; Teresa Witczak; Mirosław Grzesik; Mariusz Witczak


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
169 KB
Volume
41
Category
Article
ISSN
0538-8066

No coin nor oath required. For personal study only.

✦ Synopsis


Abstract

Esterification reactions of acrylic acid with n‐propanol and n‐butanol were carried out in the liquid phase in the presence of H~3~PW~12~O~40~ or H~3~PMo~12~O~40~ as a catalyst, at various temperatures, molar ratios of the reactants, and concentrations of the catalyst. The kinetic equations had a nonelementary form. © 2008 Wiley Periodicals, Inc. Int J Chem Kinet 41: 12–17, 2009


📜 SIMILAR VOLUMES


Kinetics and mechanism of reaction betwe
✍ Mieczysław Kucharski; Renata Lubczak 📂 Article 📅 1998 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 251 KB 👁 2 views

The reactions of acrylic and methacrylic acids in ethylene oxide, propylene oxide, or glycerin epichlorohydrin were carried out in DMF in the presence of N,N-dimethylaniline catalyst. The kinetic equations describing these equations have been devised and activation parameters and \*Hj, \*Sj, \*Gj ca

Synthesis of polyetherols with isocyanur
✍ Jacek Lubczak 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 344 KB

## Abstract To establish the mechanism of reaction of formation of oligoetherols with perhydro‐1,3,5‐triazine ring, the kinetics of reaction of isocyanuric acid and 1,3,5‐tris(2‐hydroxyetyl) isocyanurate with ethylene carbonate resulting in formation of polyetherols in the presence of diazabicyclo[