𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Kinetics of the solvolysis of [Co(Rpy)4Cl4]+with R = 4-t-Bu, 3-Me or 3-Et in mixtures of urea with water

✍ Scribed by Gehan M. El-Subruiti; Kamal H. Halawani; Cecil F. Wells; Ibrahim M. Sidahmed


Book ID
104664864
Publisher
Springer
Year
1993
Tongue
English
Weight
499 KB
Volume
18
Category
Article
ISSN
0340-4285

No coin nor oath required. For personal study only.


πŸ“œ SIMILAR VOLUMES


Kinetics of the solvolysis of [Co(3Rpy)4
✍ Gehan M. El-Subruiti; Cecil F. Wells; Ibrahim M. Sidahmed πŸ“‚ Article πŸ“… 1992 πŸ› John Wiley and Sons 🌐 English βš– 687 KB

## Abstract Rates of solvolysis of complex ions [Co(3Rpy)~4~Cl~2~]^+^ with R = __Me__ and __Et__ have been determined in mixtures of water with __t__‐butyl alcohol over a range of temperatures. Extrema found in the enthalpy Ξ”__H__\* and entropy Ξ”__S__\* of activation are correlated with the physica

Kinetics of the solvolysis of [Co(3Rpy)4
✍ Gehan M. El-subruiti; Cecil F. Wells; Ibrahim M. Sidahmed πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 English βš– 639 KB

Rates of solvolysis of complex ions [C0(3Rpy)~Cl~]+ with R = Me and Et have been determined in mixtures of water with the hydrophobic co-solvent propan-2-01 for a range of temperatures. The variations of the enthalpies and entropies of activation with the solvent composition have been correlated wit

Kinetics of the solvolysis of [Co(3Rpy)4
✍ Gehan M. El-Subruiti; Cecil F. Wells; Ibrahim M. Sidahmed πŸ“‚ Article πŸ“… 1990 πŸ› John Wiley and Sons 🌐 English βš– 624 KB

## Abstract Rates of solvolysis of ions [Co(3Rpy)~4~Cl~2~]^+^ with __R__ = Me and Et have been measured over a range of temperatures for a series of water‐rich water + methanol mixtures to investigate the effect of changes in solvent structure on the solvolysis of complexes presenting a largely hyd

Kinetics of the solvolysis of trans-dich
✍ Kamal H. Halawani; Cecil F. Wells πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 511 KB

For the solvolysis of Co(4-t-Bupy)rClz-ions in water + methanol and water + ethanol, log (rate constant) does not vary linearly with the reciprocal of the dielectric constant. The Gibbs free energy, the enthalpy, and the entropy of activation are insensitive to changes in the solvent composition in

W 2 Cl 4 (NR 2 ) 2 (PRβ€˜ 3 ) 2 Molecules.