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Kinetics of the reduction of tetrakis (2,2′-bipyridine)-μ-oxo-di-iron(III) by 1,3-benzenediol in aqueous acidic medium

✍ Scribed by Sulaiman O. Idris; Johnson F. Iyun; Edith B. Agbaji


Book ID
106547528
Publisher
Springer
Year
2008
Tongue
English
Weight
233 KB
Volume
34
Category
Article
ISSN
0340-4285

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The kinetics of the oxidation of ascorbic acid by diaquatetrakis (2,2'-bipyridine)-p-oxo diruthenium(III) in aqueous HC104 were investigated. The dependence of the second order rate constant k2 on [H +] is given by k2 = a + b[H+] -1, indicating that both the undissociated form and the monoanion of a