𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The kinetics and mechanism of the oxidation of diaquotetrakis(2,2′-bipyridine)-μ-oxodiruthenium(III) ion by bromate in aqueous perchloric acid

✍ Scribed by Johnson Femi Iyun; Godwin Adefikayo Ayoko; Yilkur Nandul Lohdip

Book ID
108428601
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
515 KB
Volume
11
Category
Article
ISSN
0277-5387

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Oxidation of glutathione by diaquatetrak
Oxidation of glutathione by diaquatetrakis(2,2′-bipyridine)-μ-oxo diruthenium(III) ion in aqueous acidic solutions
✍ Godwin Adefikayo Ayoko; Johnson Femi Iyun; Allen T. Ekubo 📂 Article 📅 1993 🏛 Springer 🌐 English ⚖ 239 KB

The kinetics of the oxidation of glutathione by diaquatetrakis(2,2'-bipyridine)-#-oxo diruthenium(III) ion in aqueous HC104 have been investigated. The reaction obeys the empirical rate law: where k=7.42\_+0.40• -1 at 25.5~ [H+]= 0.005-0.05 M and I = 1.0 M (LiC104). Free radicals are important in