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Kinetics of the reduction of pyridinium ions by 2-hydroxy-2-propyl radicals in aqueous solution

✍ Scribed by Shimura, Makoto; Espenson, James H.

Book ID
127271551
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
469 KB
Volume
22
Category
Article
ISSN
0020-1669

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πŸ“œ SIMILAR VOLUMES

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Rate Constants for the Addition of 2-Hydroxy-2-propyl Radicals to Alkenes in Solution studied by laser flash photolysis
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Absolute rate constants for the addition of the highly nucleophilic 2-hydroxy-2-propyl radical to eight fast-reacting 1and 1,l-disubstituted alkenes in MeOH at room temperature have been determined by laser flash photolysis. Also the absorption spectra of the 2-hydroxy-2-propyl and the benzylic and

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Absolute rate constants for the addition of the 2-hydroxy-2-propyl radical to 18 substituted alkenes (CH2 = C X Y ) were determined at (296 -+ 1) Kin 2-propanol by time-resolved electronspin-resonance spectroscopy. With alkene substitution the rate constants vary by more than 6 orders of magnitude.