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Kinetics of the reduction of nitrotoluenes by aqueous ammonium sulfide under liquid–liquid phase transfer catalysis

✍ Scribed by Sunil K. Maity; Narayan C. Pradhan; Anand V. Patwardhan


Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
371 KB
Volume
301
Category
Article
ISSN
0926-860X

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Reaction of benzyl chloride with ammoniu
✍ Sunil K. Maity; Narayan C. Pradhan; Anand V. Patwardhan 📂 Article 📅 2006 🏛 Elsevier Science 🌐 English ⚖ 610 KB

The reaction between benzyl chloride and aqueous ammonium sulfide was carried out in an organic solvent -toluene, using tetrabutylammonium bromide (TBAB) as phase transfer catalyst (PTC). Two products, namely dibenzyl sulfide (DBS) and benzyl mercaptan (BM), were identified in the reaction mixture.